首次分析1比特量化中直通估计器的样本复杂度，揭示数据量对训练成功的关键作用。

Training quantized neural networks requires addressing the non-differentiable and discrete nature of the underlying optimization problem. To tackle this challenge, the straight-through estimator (STE) has become the most widely adopted heuristic, allowing backpropagation through discrete operations by introducing biased yet valid surrogate gradients. However, its theoretical properties remain largely unexplored, with few existing analyses focus on the generalization error by assuming an infinite amount of training data. In contrast, this work presents the first sample complexity analysis of STE in the context of neural network quantization. Our theoretical results highlight the critical role of sample size in the success of STE, a key insight absent from existing studies. Specifically, by analyzing the quantization-aware training of a two-layer neural network with binary weights and activations, we derive the sample complexity bounds in terms of the data dimensionality that guarantee the convergence of STE-based optimization to the global minimum for both ergodic and non-ergodic analyses. Moreover, in the presence of label noises, we prove an intriguing recurrence property of STE-gradient method, where the iterate repeatedly escape from and return to the optimal binary weights. Finally, we empirically demonstrate that STE fails for general non-Gaussian data but its effectiveness can be restored through normalization, underscoring its practical importance in effective quantization.