构建首个电解器多场景高光谱数据集，助力电子废弃物材料精准识别。

The global challenge of sustainable recycling demands automated, fast, and accurate, state-of-the-art (SOTA) material detection systems that act as a bedrock for a circular economy. Democratizing access to these cutting-edge solutions that enable real-time waste analysis is essential for scaling up recycling efforts and fostering the Green Deal. In response, we introduce \textbf{Electrolyzers-HSI}, a novel multimodal benchmark dataset designed to accelerate the recovery of critical raw materials through accurate electrolyzer materials classification. The dataset comprises 55 co-registered high-resolution RGB images and hyperspectral imaging (HSI) data cubes spanning the 400--2500 nm spectral range, yielding over 4.2 million pixel vectors and 424,169 labeled ones. This enables non-invasive spectral analysis of shredded electrolyzer samples, supporting quantitative and qualitative material classification and spectral properties investigation. We evaluate a suite of baseline machine learning (ML) methods alongside SOTA transformer-based deep learning (DL) architectures, including Vision Transformer, SpectralFormer, and the Multimodal Fusion Transformer, to investigate architectural bottlenecks for further efficiency optimisation when deploying transformers in material identification. We implement zero-shot detection techniques and majority voting across pixel-level predictions to establish object-level classification robustness. In adherence to the FAIR data principles, the electrolyzers-HSI dataset and accompanying codebase are openly available at https://github.com/hifexplo/Electrolyzers-HSI and https://rodare.hzdr.de/record/3668, supporting reproducible research and facilitating the broader adoption of smart and sustainable e-waste recycling solutions.