用图像和机器学习精准测算等离子体氧化剂浓度,误差极小。
A Novel Method to Determine Total Oxidant Concentration Produced by Non-Thermal Plasma Based on Image Processing and Machine Learning
- 通过分析碘化钾溶液颜色变化的图像特征,结合机器学习建模。
- 预测准确率R2超0.998,优于传统滴定法。
- 适合等离子体化学、环境治理领域研究人员参考。
非热等离子体处理水体系中总氧化剂浓度[Ox]tot的精确测定仍面临挑战,原因在于活性氧氮物种的瞬态特性以及传统滴定法主观性强。本研究提出一种基于颜色的计算机分析方法,融合先进图像处理与机器学习技术,量化氧化过程中碘化钾溶液的颜色变化。自建视觉采集系统记录了等离子体处理期间高分辨率视频,同时利用标准滴定法同步监测氧化剂浓度变化。从提取的图像帧中生成RGB、HSV和Lab颜色特征,并通过统计分析发现部分颜色特征与实测氧化剂浓度呈强线性关系,尤其是HSV饱和度、Lab a/b通道及RGB蓝色分量。基于这些特征训练并验证了线性回归、岭回归、随机森林、梯度提升与神经网络等模型,其中线性回归与梯度提升表现最优,R2值超过0.99。通过降维将九个特征缩减至更小子集,在保持预测性能的同时提升计算效率。与实验滴定结果对比表明,该系统对碘化钾溶液中总氧化剂浓度的预测精度极高,即使在特征减少条件下,仍实现R2 > 0.998。
原文摘要 · Abstract (English)
Accurate determination of total oxidant concentration [Ox]tot in nonthermal plasma treated aqueous systems remains a critical challenge due to the transient nature of reactive oxygen and nitrogen species and the subjectivity of conventional titration methods used for [Ox]tot determination. This study introduces a color based computer analysis method that integrates advanced image processing with machine learning to quantify colorimetric changes in potassium iodide solutions during oxidation. A custom built visual acquisition system recorded high resolution video of the color transitions occurring during plasma treatment while the change in oxidant concentration was simultaneously monitored using a standard titrimetric method. Extracted image frames were processed through a structured pipeline to obtain RGB, HSV, and Lab color features. Statistical analysis revealed strong linear relationships between selected color features and measured oxidant concentrations, particularly for HSV saturation, Lab a and b channels, and the blue component of RGB. These features were subsequently used to train and validate multiple machine learning models including linear regression, ridge regression, random forest, gradient boosting, and neural networks. Linear regression and gradient boosting demonstrated the highest predictive accuracy with R2 values exceeding 0.99. Dimensionality reduction from nine features to smaller feature subsets preserved predictive performance while improving computational efficiency. Comparison with experimental titration measurements showed that the proposed system predicts total oxidant concentration in potassium iodide solution with very high accuracy, achieving R2 values above 0.998 even under reduced feature conditions.
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