提出更优的对角预条件方法，兼顾计算效率与实际迭代性能。

We study optimal diagonal preconditioning using the classical worst-case $κ$-condition number and the averaging-based $ω$-condition number. For the $κ$-optimal preconditioning problem, we derive an affine-based pseudoconvex reformulation with three key advantages: all stationary points are global minima, subgradients are inexpensive to compute, and the optimization variable is an $n$-dimensional vector rather than an $n\times n$ matrix as in semidefinite programming (SDP) approaches. We develop a simple and highly efficient subgradient method, with convergence guarantees, for solving this pseudoconvex formulation that is substantially more scalable and accurate than existing SDP-based methods. For the $ω$-condition number, we provide explicit characterizations of optimal diagonal and block diagonal preconditioners. In particular, we show that several classical preconditioners, including Jacobi and row/column normalization, are $ω$-optimal, and that matrix balancing schemes monotonically reduce $ω$ and converge to stationary points of the two-sided problem. To the best of our knowledge, this is the first unified and explicit characterization of optimality conditions for both $κ$ and $ω$-based preconditioning. Our numerical experiments further reveal a striking phenomenon: although $κ$-optimal preconditioners achieve stronger reductions in the worst-case condition number, $ω$-optimal preconditioners are substantially cheaper to compute and yield better performance for iterative methods such as preconditioned conjugate gradient (PCG) and least squares method (LSQR). Moreover, applying $ω$-optimal scaling to linear systems that are already $κ$-optimally preconditioned leads to further improvements in PCG iterations.