arXiv:2509.26234cs.LGcs.SY2025-09中稿 · presentation at Am…

用高斯过程检测锂电池快充时的锂析出,更准更稳。

Machine Learning Detection of Lithium Plating in Lithium-ion Cells: A Gaussian Process Approach

  • 直接建模电荷-电压关系,用概率方法推导微分曲线
  • 在0.2C~1C、0~40°C下准确识别出4.0V以上次峰特征
  • 适合嵌入式电池管理系统,可实时预警安全风险

快充过程中锂析出是导致电池容量衰减和安全隐患的关键退化机制。已有研究发现,析出开始会在增量容量分析中表现为4.0 V以上的额外高电压特征,常呈现为与主要嵌入峰复杂的次峰或肩部;但传统dQ/dV计算依赖有限差分加滤波,会放大传感器噪声并引入特征位置偏差。本文提出一种高斯过程(GP)框架,将电荷-电压关系Q(V)建模为带有校准不确定性的随机过程。利用高斯过程导数仍为高斯过程的性质,可从后验分布中解析、概率性地推断dQ/dV,实现无需人为平滑的鲁棒检测。该框架具备三大优势:(i) 噪声感知推理,超参数由数据学习;(ii) 导数闭式解及可信区间,实现不确定性量化;(iii) 可扩展至适用于嵌入式电池管理系统的在线版本。在不同充放电倍率(0.2C–1C)和温度(0–40℃)下的锂离子扣式电池实验表明,该方法在低温、高倍率充电条件下可靠分辨出明显的高电压次峰特征,而在无析出情况下则未报告异常特征。GP识别的微分特征与电荷容量减少、参考性能测试测得的容量衰减以及剖解显微镜验证结果一致,支持这些信号为析出相关,为实时锂析出检测提供了可行路径。

原文摘要 · Abstract (English)

Lithium plating during fast charging is a critical degradation mechanism that accelerates capacity fade and can trigger catastrophic safety failures. Recent work has shown that plating onset can manifest in incremental-capacity analysis as an additional high-voltage feature above 4.0 V, often appearing as a secondary peak or shoulder distinct from the main intercalation peak complex; however, conventional methods for computing dQ/dV rely on finite differencing with filtering, which amplifies sensor noise and introduces bias in feature location. In this paper, we propose a Gaussian Process (GP) framework for lithium plating detection by directly modeling the charge-voltage relationship Q(V) as a stochastic process with calibrated uncertainty. Leveraging the property that derivatives of GPs remain GPs, we infer dQ/dV analytically and probabilistically from the posterior, enabling robust detection without ad hoc smoothing. The framework provides three key benefits: (i) noise-aware inference with hyperparameters learned from data, (ii) closed-form derivatives with credible intervals for uncertainty quantification, and (iii) scalability to online variants suitable for embedded BMS. Experimental validation on Li-ion coin cells across a range of C-rates (0.2C-1C) and temperatures (0-40$^\circ$C) demonstrates that the GP-based method reliably resolves distinct high-voltage secondary peak features under low-temperature, high-rate charging, while correctly reporting no features in non-plating cases. The concurrence of GP-identified differential features, reduced charge throughput, capacity fade measured via reference performance tests, and post-mortem microscopy confirmation supports the interpretation of these signatures as plating-related, establishing a practical pathway for real-time lithium plating detection.

电池健康高斯过程锂析出故障预警

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