首个大规模射频材料识别数据集，支持高精度材质分类与跨场景鲁棒性测试。

Accurate material identification plays a crucial role in embodied AI systems, enabling a wide range of applications. However, current vision-based solutions are limited by the inherent constraints of optical sensors, while radio-frequency (RF) approaches, which can reveal intrinsic material properties, have received growing attention. Despite this progress, RF-based material identification remains hindered by the lack of large-scale public datasets and the limited benchmarking of learning-based approaches. In this work, we present RF-MatID, the first open-source, large-scale, wide-band, and geometry-diverse RF dataset for fine-grained material identification. RF-MatID includes 16 fine-grained categories grouped into 5 superclasses, spanning a broad frequency range from 4 to 43.5 GHz, and comprises 142k samples in both frequency- and time-domain representations. The dataset systematically incorporates controlled geometry perturbations, including variations in incidence angle and stand-off distance. We further establish a multi-setting, multi-protocol benchmark by evaluating state-of-the-art deep learning models, assessing both in-distribution performance and out-of-distribution robustness under cross-angle and cross-distance shifts. The 5 frequency-allocation protocols enable systematic frequency- and region-level analysis, thereby facilitating real-world deployment. RF-MatID aims to enable reproducible research, accelerate algorithmic advancement, foster cross-domain robustness, and support the development of real-world application in RF-based material identification.