首次揭示移动端大模型推理中NPU的隐藏能效瓶颈，提出优化配置可省电超5成。

Deploying Large Language Models (LLMs) on mobile devices enhances privacy and reduces latency, but is severely bottlenecked by hardware inefficiency. We present the first comprehensive, cross-layer measurement study of mobile LLM inference, uniquely spanning five mainstream frameworks (e.g., llama.cpp, GENIE) and three hardware backends (CPU, GPU, NPU). To enable this analysis, we develop PowerBench, a fine-grained profiling tool that provides the first backend-specific energy attribution, moving beyond traditional device-level measurements. Our study yields three critical insights: (1) Framework-induced performance gaps are substantially amplified on NPUs, reaching up to 10x using custom operators due to divergent offloading and quantization strategies. (2) We identify a distinct phase split where NPUs excel at compute-bound prefilling, while CPUs outperform all other backends in memory-bound decoding. This is driven by the NPU's preference for large, fixed-shape workloads, which conflicts with the small-kernel, dynamic nature of decoding. (3) Backend-specific profiling uncovers substantial scheduling headroom missed by prior work. Suboptimal thread configurations, uncoordinated NPU sleep latencies, and CPU polling intervals result in up to 40% energy waste. Leveraging these findings, we present an energy-oriented best-practice configuration for mobile LLM inference. We estimate that this configuration could reduce energy consumption by up to 54.8% on the NPU backend across three datasets.