将电池退化物理规律融入神经网络,提升健康状态预测准确性与合理性。
PiDDM: Physics-Informed Differentiable Degradation Modeling for Lithium-Ion Battery State-of-Health Prediction

- 在损失函数中引入阿伦尼乌斯退化动力学,约束容量衰减的物理一致性。
- 在55块电池上测试,平均误差最低,外推阶段比基线模型降低显著均方误差。
- 适合需要长期可靠预测的电池管理系统,尤其关注真实退化行为建模者。
锂离子电池健康状态(SOH)的准确预测对储能系统可靠运行至关重要。然而,纯数据驱动模型在不同循环策略下泛化能力差,且长期外推时可能出现物理上不合理的容量回升。本文提出一种物理信息可微退化建模框架(PiDDM),将固态电解质界面生长和锂库存损失相关的阿伦尼乌斯经验退化动力学纳入训练目标,以确保在多种工况下容量衰减具有物理一致性。该框架在包含55块电池、6种循环协议的公开数据集上进行评估。所有模型均在每块电池前90%寿命周期数据上训练,后10%作为未见测试数据进行外推评估。PiDDM在所有模型中实现最低平均预测误差,并显著降低相对于多层感知机和基线物理信息神经网络的均方误差。在长期外推中,PiDDM成功捕捉到寿命末期加速退化趋势,而避免了基线模型产生的非物理解释性容量回升。结果表明,将退化物理规律嵌入神经网络训练能有效提升预测精度与物理合理性,为实际电池健康监测提供可行方案。
原文摘要 · Abstract (English)
Accurate prediction of lithium-ion battery state of health (SOH) is essential for reliable energy storage operation. However, purely data-driven models may generalize poorly across cycling protocols and produce physically implausible behavior during long-term extrapolation. We developed a physics-informed differentiable degradation modeling framework (PiDDM) for battery SOH prediction. PiDDM incorporates empirical Arrhenius degradation kinetics associated with solid electrolyte interphase growth and loss of lithium inventory into the training objective, encouraging physically consistent capacity fade under diverse operating conditions. The framework was evaluated using a public dataset of 55 batteries cycled under six operating protocols. PiDDM achieved the lowest average prediction error among the evaluated models and substantially reduced mean squared error relative to a multilayer perceptron and a baseline physics-informed neural network. For extrapolation, the models were trained on the first 90% of each battery's cycle life and evaluated on the unseen final 10%. PiDDM captured accelerated end-of-life degradation while avoiding the nonphysical capacity regeneration produced by the baseline models. These results show that incorporating degradation physics into neural network training improves predictive accuracy and physical consistency, providing a promising approach for practical battery health monitoring.
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