用双教师对比提升大模型合规性，不损失正常功能。

Real-world LLM deployments increasingly rely on runtime-injected prohibitions--enterprise policies, PII redlines, tool boundaries--that vary per request and per tenant. Conventional post-training is structurally ill-suited: SFT hides the violation signal in compliant labels, and DPO's sequence-level preferences mismatch token-localized violations. We propose DUET, a token-selective on-policy distillation method for prohibition compliance. DUET pairs a teacher that sees the prohibition (positive) with an identical-weight teacher that does not (negative). Because the two teachers differ only in prohibition visibility, their per-token disagreement isolates the prohibition's causal effect--yielding a clean supervision signal uncontaminated by model capacity or mismatch. This disagreement drives two complementary mechanisms: signal cleaning, which discards agreement tokens as redundant or prefix-corrupted, and preference-directed learning, which pushes the student away from the negative teacher and toward the positive one at token granularity, embedding DPO-style optimization directly into OPD without offline preference data. We construct an industrial Prohibition-Compliance benchmark spanning five task families covering explicit-refusal, paraphrase robustness, and over-refusal. Across 1.5B-8B Qwen variants, DUET achieves 72.3-85.2% violation compliance while preserving 88-93% normal utility, dramatically outperforming teacher model and other distillation baselines. External evaluation on SysBench confirms improved safety alignment with minimal degradation on GSM8K and MATH-500.